Montmorillonite clay naturally forms stacks of plate-like structures, or platelets.
Each platelet is less than 10 Angstroms thick, but over 200 times that in width.
The spaces between these platelets are called gallery spaces.
For a description of the molecular structure of the clay plates, click here.  It is difficult to describe just
how much surface area the clay platelets have.  They are so incredibly thin, though, that a small mass of
clay has a disproportionately large surface area.  Think of it this way.  A dumptruck full of sheets of paper would be carrying way more surface area than a dumptruck full of beachballs, or even baseballs.
 




Under the proper conditions, the gallery spaces can be filled with monomer, oligomer, or polymer. This increases the distance between platelets, swelling the clay. Clay platelets swollen with polymer are said to be intercalated.

If the clay swells so much that it is no longer organized into stacks, it is said to be exfoliated.

Intercalated Material
Exfoliated Material

Modification of clay
Nanocomposites page 1